1. In a large mixing bowl, combine rye flour, all-purpose flour, caraway seeds, and salt.
2. In a separate bowl, dissolve brown sugar and molasses in warm water. Add orange zest and yeast. Let it sit for 5-10 minutes until frothy.
3. Pour the wet ingredients into the dry ingredients and mix until a dough forms.
4. Knead the dough on a floured surface for about 10 minutes until smooth and elastic.
5. Place the dough in a greased bowl, cover with a damp cloth, and let it rise in a warm place for about 1 hour or until doubled in size.
6. Preheat your oven to 375°F (190°C).
7. Punch down the dough, shape it into a loaf, and place it on a baking sheet.
8. Bake for 30 minutes or until the bread sounds hollow when tapped on the bottom.
9. Let the bread cool on a wire rack before slicing.